Polymers are substances whose molecules have high molar masses and are composed of a large number of repeating units. There are both naturally occurring and synthetic polymers. Among naturally occurring polymers are proteins, starches, cellulose, and latex. Synthetic polymers are produced commercially on a very large scale and have a wide range of properties and uses. The materials commonly called plastics are all synthetic polymers.

Polymers are formed by chemical reactions in which a large number of molecules called monomers are joined sequentially, forming a chain. In many polymers, only one monomer is used. In others, two or three different monomers may be combined. Polymers are classified by the characteristics of the reactions by which they are formed. If all atoms in the monomers are incorporated into the polymer, the polymer is called an addition polymer. If some of the atoms of the monomers are released into small molecules, such as water, the polymer is called a condensation polymer. Most addition polymers are made from monomers containing a double bond between carbon atoms. Such monomers are called olefins, and most commercial addition polymers are polyolefins. Condensation polymers are made from monomers that have two different groups of atoms which can join together to form, for example, ester or amide links. Polyesters are an important class of commercial polymers, as are polyamides (nylon).

POLYACRYLAMIDE

             Polyacrylamide is a condensation polymer with an unusual and useful property. The structure of polyacrylamide is similar to that of polyethylene, but having a hydrogen on every other carbon replace by an amide group, –CONH₂. The molecule is composed of repeating –CH₂–CH(CONH₂)– units. The amide groups allow for linking between polymer strands. The –CONH₂ group from one molecule can react with the same group of another molecule, forming a link between them with the structure –CONHCO–. This produces a network of polymer chains, rather like a tiny sponge. The free, unlinked amide groups, because they contain –NH₂ groups, can form hydrogen bonds with water. This gives the tiny cross linked sponges a great affinity for water. Polyacrylamide can absorb many times its mass in water. This property is useful in a variety of applications, such as in diapers and in potting soil. The polyacrylamide will release the absorbed water if a substance that interferes with hydrogen bonding is added. Ionic substances, such as salt, cause polyacrylamide to release its absorbed water. [For more information about this polymer, see Ibid., Volume 3 (1989), page 368.]

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Courtisy of University of Wisconsin-Madison Chemistry Professor Bassam Z. Shakhashiri & http://www.scifun.org/